王涛

讲师，硕士生导师

邮箱：kfwang0001@126.com

个人简介

主持完成省教育厅项目2项，与其他学校和企业合作完成横向课题3项。在Chem. Eur. J., Adv. Synth. Catal.，J. Org. Chem.，Dalton Trans.等国内外重要学术期刊发表论文十余篇，授权发明专利4件。指导8名硕士研究生。获河南大学优秀辅导员，河南省天然药物与免疫工程重点实验室优秀共产党员。

教育经历

2015-09 至 2019-06, 天津大学, 化学，博士

博士后工作经历

   2015-05 至 2017-07, 河南大学

科研与学术工作经历

2024-03 至 今, 河南大学, 河南省天然药物创新与转化重点实验室, 讲师

2019-01 至 2024-03, 河南大学, 河南省天然药物与免疫工程重点实验室, 讲师

研究方向

主要从事Z-选择性钌卡宾烯烃复分解催化剂的设计，有机小分子的不对称催化研究。

主持科研项目

1. 河南教育厅，新型高效Z-选择性钌卡宾烯烃复分解催化剂的开发，2021.01.01-2022.12.31，主持，结项。

2. 河南教育厅，油酸甲酯乙烯解制备1-癸烯催化剂的合成及工业化研究，2023.01.01-2024.12.31，主持，在研。

3. 中国科学院大学，Grubbs二代和三代催化剂在不同环境中和两种温度下的稳定性研究，2020.12.11-2021.04.30，10万，结项。

4. 企业，Ru卡宾烯烃复分解催化剂催化油酸甲酯乙烯解制1-癸烯，2022.11.24-2024.05.25，40万，结项。

5. 企业，专利转化，一种Z-选择性钌卡宾烯烃复分解催化剂及其制备方法和应用，20万，完成。

代表性研究论文

1. Zhen-Zhen Sun, Pan Gao, Yong Yang, Tao Wang,* Xiao-Jun Wu, You-Qing Wang.* Synthesis of Carboranylated Dihydropyrrolo[1,2‑a]quinoxalines and Dihydroindolo[1,2‑a]quinoxalines by BF3•OEt2-Catalyzed Heterocyclization of C‑Formyl‑o‑carboranes and Investigation of Their Oxidation Stability. J. Org. Chem. 2024, 89, 3573−3579

2. Ying Du, Qian Li, Tao Wang*, You-Qing Wang*, Enantioselective Synthesis of Biphenyl-bridged ε-Sultams by Organocatalytic Mannich Reactions of Cyclic N-Sulfonylimines with Unactivated Ketones, Chem. Eur. J. 2023, DOI: 10.1002/chem.202302904.

3. Tao Wang, Bo Huang, You-qing Wang*. Enantioselective Synthesis of Spiro Chroman-Isoindolinones via Formal (4+2) Cycloaddition of In Situ-Generated ortho-Quinone Methides with 3-Methylene Isoindolinones, Adv. Synth. Catal. 2022, 364, 2596–2605.

4. Huiqing Zhang, Jiaren Zhang, Peng Ma, Tao Wang*, Jianhui Wang*. Synthesis and catalysis of a Z-stereoretentive ruthenium carbene catalyst chelated by 2,4,5,7-tetrachloro-1,8-dimercaptonaphthalene for olefin metathesis. New J. Chem., 2022, 46, 7669–7674

5. Tao Wang, Qingxiao Xie, Weijie Guo, Shutao Wu, Huiqing Zhang, Jianhui Wang*, Botao Wu. 3,4-Dioxocyclobut-1-ene-1,2-dithiolate-chelated Ruthenium Carbene Catalyst for Z-Stereoretentive/ Stereoselective Olefin Metathesis. Dalton Trans. 2019, 48, 6473-6483.

6. Tao Wang, Botao Wu, Yulian Duan, Weijie Guo, Shutao Wu, Huiqing Zhang, Yanfeng Dang*, Jianhui Wang*. Synthesis, Catalysis, and DFT Study of A Ruthenium Carbene Complex Bearing A 1,2-Dicarbadodecaborane (12)-1,2-Dithiolate Ligand. Dalton Trans. 2019, 48, 2646-2656.

7. Tao Wang, Xiaobo Yu, Huiqing Zhang, Shutao Wu, Weijie Guo, Jianhui Wang*. Synthesis and Evaluation of Ruthenium 2-Alkyl-6-mercaptophenolate Catalysts for Olefin Metathesis. Appl. Organomet. Chem. 2019, 33, e4939.

8. Tao Wang, Qingxiao Xie, WeijieGuo, Shutao Wu, Huiqing Zhang, Jianhui Wang*. Synthesis and Evaluation of Naphthalene-1, 8-Dithiolate Chelating Ruthenium Carbene Catalyst for Z-Stereoretentive Olefin Metathesis. J. Organomet. Chem. 2019, 880, 62-67.

9. Tao Wang, Bo Dong, Yanhui Chen, Guoliang Mao, Tao Jiang*. Nickel complexes incorporating pyrazole-based ligands for ethylene dimerization to 1-butylene. J. Organomet. Chem. 2015, 798, 388-392.

10. Tao Wang, Xianglu Gao, Pengfei Shi, Haixiang Pei, Tao Jiang*. Mixed aluminoxanes: efficient cocatalysts for bisphosphineamine/Cr(III) catalyzed ethylene tetramerization toward 1-octene. Appl. Petrochem. Res. 2015, 5, 143-149.

合著论文：

1. Yulian Duan, Tao Wang, Qingxiao Xie, Xiaobo Yu, Weijie Guo, Jianhui Wang*, Guiyan Liu*. Highly efficient nitrogen chelated ruthenium carbene metathesis catalysts. Dalton Trans., 2016, 45, 19441- 19448.

2. Yulian Duan, Tao Wang, Qingxiao Xie, Xiaobo Yu, Weijie Guo, Shutao Wu, Danfeng Li, Jianhui Wang*, Guiyan Liu*. A pH-controlled recyclable indolinooxazolidine tagged N-heterocyclic carbene Ru catalyst for olefin metathesis. Dalton Trans., 2017, 46, 5986-5993.

3. Qingxiao Xie, Tao Wang, Shutao Wu, Weijie Guo, Huiqing Zhang, Jianhui Wang*. A Stable Ruthenium Complex Bearing a 1,2-Dicarbadodecaborane(12)-1, 2-Dithiolate Ligand and Its Activation for Olefin Metathesis. J. Organomet. Chem., 2018, 865, 95-99.

4. Shutao Wu, Weijie Guo, Tao Wang, Qingxiao Xie, Jianhui Wang*, Guiyan Liu*. Formation of Tertiary Alcohol via Chelation-Assisted Nickel(II)-Catalyzed Addition of Arylboronic Acids to Unactivated 1-(Quinolin-8-yl)ethan-1-one. Adv. Synth. Catal., 2018, 360, 4533-4542.

5. Shutao Wu, Siyuan Luo, Weijie Guo, Tao Wang, Qingxiao Xie, Jianhui Wang*, Guiyan Liu*. Direct Conversion of Ethyl Ketone to Alkyl Ketone via Chelation-Assisted Rhodium(I)-Catalyzed Carbon-Carbon Bond Cleavage: Ligands Play an Important Role in the Inhibition of β-Hydrogen Elimination. Organometallics, 2018, 37, 2335-2341.

6. Xiaobo Yu, Yulian Duan, Weijie Guo, Tao Wang, Qingxiao Xie, Shutao Wu, Chenggong Jiang, Zixiong Fan, Jianhui Wang*, Guiyan Liu*. Rhodium-Catalyzed Oxidative Decarboxylation Annulation Reactions of Mandelic Acids and Alkynes: An Efficient Synthetic Method for Indenones. Organometallics, 2017, 36, 1027-1034.

授权专利

1. Z-选择性钌卡宾烯烃复分解催化剂及其制备方法和应用，授权号：CN 113000066B。