石家华-河南大学天然药物与免疫工程重点实验室

石家华，男，博士，教授，博士生导师，河南大学特聘教授（生物材料）。1972年2月出生，1995年毕业于河南大学化学化工系，2005年获得中科院化学所博士学位，2006.2-2009.1年在新加坡国立大学从事博士后研究。河南省高校青年骨干教师，河南省教育厅学术技术带头人，河南省学术技术带头人，开封市优秀教师。先后在Carbon，Nanotechnology, J. Phys. Chem. B., J. Phys. Chem. C.，Chemistry of Materials, European Polymer Journal等刊物上发表SCI收录论文30多篇。电话：13937825383，Email：sjiahua@henu.edu.cn

教育经历：

工作经历：

研究兴趣:

©纳米载药体系的设计与合成；

©碳纳米材料及其复合材料；

©导电聚合物基纳米复合材料

奖励与荣誉：

©河南省高校青年骨干教师（2009）；

©河南省教育厅学术技术带头人（2010）；

©Covalently Attached Multilayer Self-assemblies of Single-walled Carbon Nanotubols and Diazoresins，河南省自然科学优秀学术论文一等奖(2010年)，第一完成人

©开封市优秀教师，河南大学师德先进个人（2011）。

科研项目：

曾经参与完成多项国家和省部级科研项目，正主持以下科研项目：

©国家自然科学基金面上项目（2011-2013, No: 21073054 ）；

©省级自然科学基金(2010-2012, No: 102300410180);

©省部共建项目(2010-2012, No: SBGJ090708)

©河南省高校青年骨干教师资助计划(2010-2012, No: 2009GGJS-021)；

©河南省教育厅重点科研项目(2014-2015, No: 14A430013)

代表性论文：

1. Jiahua Shi, Yujun Qin, Wei Wu, Xianglong Li, Zhi-Xin Guo, Daoben Zhu. In situ Synthesis of CdS Nanoparticles on Multi-walled Carbon Nanotubes, Carbon, 2004, 42, 465-468.

2. Jiahua Shi, Zhi-Xin Guo, Bohan Zhan, Yongfang Li, Daoben Zhu. Actuators Based on PVA/MWNT Hydrogels, J. Phys. Chem. B, 2005, 109, 14789-14791.

3. Jiahua Shi, Yujun Qin, Zhi-Xin Guo, Daoben Zhu. Covalently attached multilayer Self-Assemblies of Single-Walled Carbon Nanotubols and Diazoresins, Nanotechnology, 2007, 18, 365704.

4. Jiahua Shi, Zhiyong Chen, Yujun Qin, Zhi-Xin Guo. Multiwalled Carbon Nanotube Microspheres from Layer-by-Layer Assembly and Calcination, J. Phys. Chem. C, 2008, 112, 11617-11622.

5. Jia-Hua Shi, Bing-Xing Yang, K. P. Pramoda, Suat Hong Goh. Enhancement of the Mechanical Performance of Poly(vinyl chloride) Using Poly(n-butyl methacrylate)-grafted Multiwalled Carbon Nanotubes, Nanotechnology, 2007, 18, 375704.

6. Jia-Hua Shi, Bing-Xing Yang, Suat Hong Goh. Covalent functionalization of multiwalled carbon nanotubes with poly(styrene-co-acrylonitrile) by reactive melt blending, European Polymer Journal, 2009, 45 1002-1008.

7. Jia-Hua Shi, Tao Wen, Binni Varghese, Minrui Zheng, Chorng-Haur Sow, Hardy S. O. Chan. One-Pot Synthesis and Electrical Characterization of Monodisperse Solid Polyaniline Sub-Microspheres, Advanced Science Letters, 2011, 4, 449-457.

8. Qiang Wu, Chaoqun Liu, Luna Fan, Jiahua Shi*, Zhiqiang Liu, Ruifang Li, Liwei Sun. Heparinized magnetic mesoporous silica nanoparticles as multifunctional growth factor delivery carriers, Nanotechnology, 2012, 23 (48), 485703.

9. Qiang Wu, Chaoqun Liu, Luna Fan, Jiahua Shi*, Huanxia Jia, Qiaofang Qi, Zhiqiang Liu. Heparinized hierarchically hollow hydroxyapatite microspheres as bone substitute: Fabrication and controlled delivery of growth factors, RSC Advances 2013, 3, 7486-7494.

10. Jiahua Shi*, Qiang Wu, Runming Li, Yinxu Zhu, Yujun Qin, Congzhen Qiao. pH-Controlled Morphology Transition of Polyaniline from Nanofibers to Nanosphere, Nanotechnology, 2013, 24(17), 175602.

11. Along Xiong, Xuan Lu, Yiming Ma, Yujun Qin, Pu Zhang, Jiahua Shi*, Zhi-Xin Guo, Cross-linked multilayer composite films and microcapsules embedded carbon nanotubes, Materials Letters 2013, 105,132-135.

12. Yongwei Huang, Junchao Wang, Lina Fu, Wenfeng Kuang, Jiahua Shi*. Effect of Core-substituted Groups on Sensing Properties Based on Single Micro/nanorod of Perylenediimide Derivatives. Sensors and Actuators B: Chemical 2013, 188, 411-416.

13. Qiang Wu*, Qiaofang Qi, Chao Zhao, Chaoqun Liu, Luna Fan, Wenzong Zhang, Jiahua Shi* and Dongjie Guo, A hybrid proteolytic and antibacterial bifunctional film based on amphiphilic carbonaceous conjugates of trypsin and vancomycin, Journal of Materials Chemistry B, 2014, 2, 1681-1688.

14. Yuchao Ma, Mengmeng Xue, Jiahua Shi*, Yiwei Tan. Large-scale, solution-phase growth of semiconductor nanocrystals into ultralong one dimensional arrays and electrical properties. Nanoscale 2014,6, 6828-6836.

15. Quanhui Guo, Shuangshuang Zou, Juan Li, Dongfeng Li, Hexian Jiao, Jiahua Shi*, Facile synthesis of morphology- and size-controllable polythiophene/gold composites in aqueous medium. Journal of Nanoparticle Research 2014, 16, 2702.

16. Shuling Yu, Shufang Gao, Ying Gan, Yi Zhang, Xiaojiao Ruan, Yali Wang, Liu Yang, Jiahua Shi*,QSAR models for predicting octanol/water and organic carbon/water partition coefficients of polychlorinated biphenyls. GSAR SAR and QSAR in Environmental Research, 2016, doi: 10.1080/1062936X.2016.1158734.

17. Shuling Yu*, Jintao Yuan, Jiahua Shi, Xiaojiao Ruan, Yali Wang, Shufang Gao and Yu Du, One-pot synthesis of water-soluble, β-cyclodextrin-based polyrotaxanes in a homogeneous water system and its use in bio-applications. Journal of Materials Chemistry B, 2015, 3, 5277--5283.

18. Shuling Yu*, Jintao Yuan, Jiahua Shi, Xiaojiao Ruan, Ting Zhang, YanliWang, Yu Du, HQSAR and topomer CoMFA for predicting melanocortin-4 receptor binding affinities of trans-4-(4-chlorophenyl) pyrrolidine-3-carboxamides. Chemometrics and Intelligent Laboratory Systems, 2015,146, 34–41.

19. Shuling Yu*, Xuejie Yuan, Jing Yang, Jintao Yuan, Jiahua Shi, Yali Wang, Yuewen Chen, Shufang Gao, A chemometric-assisted method for the simultaneous determination of malachite green and crystal violet in water based on absorbance–pH data generated by a homemade pH gradient apparatus. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015, 150, 403–408.

20. Xianhe Huang, Mengmeng Zhang, Xinwei Dou, Xuan Lu, Yujun Qin*, Pu Zhang, Jiahua Shi*, Zhixin Guo, Strengthened graphene oxide/diazoresin multilayer composites from layer-by-layer assembly and cross-linking. Chinese Chemical Letters, 2015, 26, 1155-1157.

21. Yongwei Huang*, Weiguang Zhang, Junchao Wang, Lina Fu, Jiahua Shi*, Electron-withdrawing groups induced remarkable changes in sensory property based on single micro/nanostructure of perylenediimide derivatives. Materials Chemistry and Physics, 2015, 151, 93-98.

22. 牛菊，王新民，石家华，核－壳结构的四氧化三铁/聚多巴胺复合材料的制备及其对Zn（Ⅱ）吸附性能的研究，郑州师范教育，2014，3（4），5-8.

23. 李鹏莉，于树玲，石家华，聚多巴胺改性碳纳米管对Pb^2＋的吸附性能，河南大学学报（自然科学版），2014，44（4），416-42.

24. 李志元，李润明，石家华，纳米聚苯胺及聚苯胺/金复合材料的制备与表征，化学研究，2014，25（2），195-200.

25. 冉青彦，乔聪震，石家华，碳纳米管/聚苯胺复合材料的制备及应用研究进展，化学研究，2013，24（2），199-206.

26. 朱银旭，李润明，石家华，界面反应法制备聚苯胺及聚苯胺/金复合纳米材料，郑州师范教育，2013，2（2），13-16.

27. 刘雪，郭泉辉，石家华，CNTs/Fe3O4复合材料的制备及应用研究进展，2012，1（4），5-9.

28. 冯娟，袁金芳，石家华，pH响应两亲性嵌段聚合物胶束的制备及其对叶酸的控制释放，郑州师范教育，2015，4（2），13-19.

29. Jiahua Shi, Xun Sun, Chunhe Yang, Qingyu Gao, Yongfang Li. Electrochemical Synthesis of Polythiophene in an Ionic Liquid, Chinese Chemical Letters, 2002, 13, 306-307.

30. 石家华，杨春和，高青雨，李永舫，聚噻吩在离子液体中的电化学合成研究 化学物理学报，2004，17：503-507.

31. 石家华，孙逊，杨春和，高青雨，李永舫，离子液体的研究进展 化学通报，2002，4：243-250.

32. Yujun Qin, Jiahua Shi, Wei Wu, Xianglong Li, Zhi-Xin Guo and Daoben Zhu. Concise Route to Functionalized Carbon Nanotubes, J. Phys. Chem. B, 2003, 107, 12899-12901.

33. Yujun Qin, Luqi Liu, Jiahua Shi, Wei Wu, Jun Zhang, Zhi-Xin Guo, Yongfang Li, Daoben Zhu. Large-scale Preparation of Solubilized Carbon Nanotubes, Chemistry of Materials. 2003, 15, 3256-3260.

34. Junping Hu, Jiahua Shi, Shouping Li, Yujun Qin, Zhi-Xin Guo, Yanlin Song, Daoben Zhu. Efficient Method to Functionalize Carbon Nanotubes with Thiol Groups and Fabricate Gold Nanocomposites. Chemical Physics Letters, 2005, 401, 352-356.

35. Shouping Li, Yujun Qin, Jiahua Shi, Zhi-Xin Guo, Yongfang Li, Daoben Zhu. Electrical Properties of Soluble Carbon Nanotube/Polymer Composite Films. Chemistry of Materials, 2005, 17, 130-135.

36. Bing-Xing Yang, Jia-Hua Shi, K. P. Pramoda, Suat Hong Goh, Enhancement of Stiffness, Strength, Ductility and Toughness of Poly(ethylene oxide) Using Phenoxy-grafted Multiwalled Carbon Nanotubes. Nanotechnology, 2007, 18, 125606.

37. Mian Wang, Jia-Hua Shi, K. P. Pramoda, Suat Hong Goh, Microstructure, Crystallization and Dynamical Behavior of Poly(vinylidene fluoride) Composites Containing Poly(methyl methacrylate)-grafted Multiwalled Carbon Nanotubes. Nanotechnology, 2007, 18, 235701.

38. Xianglong Li, Jiahua Shi, Yujun Qin, Qi Wang, Hongxia Luo, Pu Zhang, Zhi-Xin Guo, Hyung-Suk Woo, Dong-Kyu Park, Alkylation and Arylation of Single-walled Carbon Nanotubes by Mechanochemical Method. Chemical Physics Letter, 2007, 444, 258-262.

39. Bing-Xing Yang, Jia-Hua Shi, Xu Li, K. P. Pramoda, Suat Hong Goh, Enhancement of the Mechanical Properties of Polypropylene Using Polypropylene-grafted Multiwalled Carbon Nanotubes. Composites Science and Technology, 2008, 68,.2490-2497.

40. Bing-Xing Yang, Jia-Hua Shi, Xu Li, K. P. Pramoda, Suat Hong Goh Mechanical Reinforcement of Poly(1-butene) Using Polypropylene-grafted Multiwalled Carbon Nanotubes. Journal of Applied Polymer Science, 2009, 113, 1165-1172.

41. Deqiang Zhao, Siew-Min Ong, Zhilian Yue, Zhiyong Jiang, Yi-Chin Toh, Majad Khan, Jiahua Shi, Choon-Hong Tan, J. Paul Chen, Hanry Yu, Dendrimer hydrazides as multivalent transient inter-cellular linkers, Biomaterials, 2008, 29, 3693–3702.

42. Suojiang Zhang, Yanqiang Zhang, Jianmin Zhang, Yuhuan Chen, Jiahua Shi, Zhixin Guo, Dispersion of modified carbon nanotubes in 1-butyl-3-methyl imidazolium tetrafluoroborate, J. Mater. Sci., 2006, 41, 3123-3126.

43. Ya-li Luo, Jin-Fang Yuan, Jia-Hua Shi, Qing-Yu Gao. Synthesis and characterization of polyion complex micelles and their controlled release of folic acid, Journal of Colloid and Interface Science, 2010, 350(1), 140-147.

44. Tianhong Qu, Airong Wang, Jinfang Yuan, Jiahua Shi, Qingyu Gao. Preparation and characterization of thermo-responsive amphiphilic triblock copolymer and its self-assembled micelle for controlled drug release, Colloids and Surfaces B: Biointerfaces, 2009, 72(1), 94-100.

45. Tao Wen, Jia-Hua Shi, Minrui Zheng, Binni Varghese, Chorng-Haur Sow, Hardy Sze On Chan. Morphology Evolution of Polyaniline Microstructures in Toluene and their Hydrophobic/Hydrophilic Properties, Journal of nanoscience and Nanotechnology, 2012, 12(1), 91-98.

46. 秦玉军，石家华，武伟，李守平，李祥龙，郭志新，朱道本. “化学修饰碳纳米管的方法 ”, 中国专利申请号：200310113304.0, 2003.

47. 秦玉军, 郭志新, 刘璐琪, 武伟, 潘华龙, 李祥龙, 石家华, 朱道本, “一种大规模制备可溶性碳纳米管的方法”, 专利申请号：03138282.7, 2003.

48. Jiahua Shi, Yujun Qin, Wei Wu, Xianglong Li and Zhixin Guo. ‘In situ Synthesis of CdS Nanoparticles on Multi-walled Carbon Nanotubes’. 全国第六届有机固体电子过程暨华人有机光电功能材料学术讨论会, 2003年10月15-18日, 武汉.

49. Yujun Qin, Jiahua Shi, Wei Wu, Xianglong Li, Zhi-Xin Guo and Daoben Zhu , ‘A concise route to chemically modified carbon nanotubes’. 全国第六届有机固体电子过程暨华人有机光电功能材料学术讨论会, 2003年10月15-18日, 武汉, PA-54.

50. Jiahua Shi, Y. J. Qin, Z-X. Guo, D. B. Zhu. ‘Self-assembly of single-walled carbon nanotubols and diazoresins’. The Tenth International Conference on Organized Molecular Films, October 5-October 10, 2004, Beijing, China.

51. Jia-Hua Shi, Tao Wen, Chorng-Haur Sow, Hardy S. O. Chan. ‘One-Pot Synthesis and Characterization of Monodisperse Solid Polyaniline Sub-Microspheres’. The 2008 Asian Conference on Nanoscience and Nanotechnology (AsiaNANO2008) November 3-7, 2008, Biopolis, Singapore.

52. Jiahua Shi “聚苯胺纳米结构和聚苯胺/纳米金复合材料的制备：pH诱导的形貌变化”. 全国第九届有机固体电子过程暨华人有机光电功能材料学术讨论会, 2012年11月10-12日, 扬州, 口头报告。